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non linear visco elasticity

Hi

 i am interested to study the morphology of polymeric membranes in non linear regime. I am in search of what actually a 'non linear behavior in a material represents'. Mathematically there are certain equations governing the non linear behavior. But my concern is how material behaves in non linear regime (under moderate to high stress). And what molecular and microstructural features contributes to the non linear behavior?. Can any one post me to under stand the micro sructural behavior of polymers in non linear regime. It would be useful help to me. 

  Rajasekhar

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