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Effect of cobalt content on the electrochemical properties and structural stability of NCA type cathode materials

Dibakar Datta's picture

  Effect of cobalt content on the electrochemical properties and structural stability of NCA type cathode materials

  Physical Chemistry Chemical Physics (PCCP)  

  Please email me if you want the PDF copy (PCCP Article Sharing Policy)

  Abstract: At present, the most common type of cathode materials, NCA (Li1-xNi0.80Co0.15Al0.05O2, x = 0 to 1),  have a very high concentration of cobalt. Since cobalt is toxic and expensive, the existing design of cathode materials is neither cost-effective nor environmentally benign. We have performed density functional theory (DFT) calculations to investigate electrochemical, electronic, and structural properties of four types of NCA cathode materials with the simultaneous decrease in Co content along with the increase in Ni content. Our results show that even if the cobalt concentration is significantly decreased from 16.70% (NCA_I) to 4.20% (NCA_IV), variation in intercalation potential and specific capacity is not significant. For example, in the case of 50% Li concentration, the voltage drop is only B17% while the change in specific capacity is negligible. Moreover, we have also explored the influence of sodium doping in the intercalation site on the electrochemical, electronic, and structural properties. By considering two extreme cases of NCAs (i.e., with highest and lowest Co content: NCA_I and NCA_IV, respectively), we have demonstrated the importance of Na doping from the structural and electronic point of view. Our results provide insight into the design of environmentally benign, low-cost cathode materials with reduced cobalt concentration.

We started this work after a stimulating discussion session with the researchers at the Tesla Motors Headquarter, Palo Alto, California.  If you are interested in this topic, you may want to read the latest development at Tesla on NCA Cathode Materials. 

Tesla releases rare details about Model 3’s battery cells, claims highest energy density and less cobalt

 Tesla’s Next-Generation Cathodes A Victory For Human Rights Advocates Against DRC’s “Artisanal Mining”

  

 Thanks, 

 Dibakar Datta

 Email - dibakar.datta[AT]njit.edu

Comments

Dibakar Datta's picture

 At present, cobalt is the crucial element for batteries. But how do we get cobalt?

 Watch this video -  

  https://www.youtube.com/watch?time_continue=498&v=OTEVHykWZqk

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