Polar dielectric based cooling devices are
modeled as a system with two degrees of freedom and represented by either an
entropy-temperature or electric displacement-electric field plane. A typical
thermodynamic energy cyclic path is proposed for polar dielectric as cooling
devices to experience. With the influence of temperature taken into
consideration, the free energy of a thermal electrical coupling system of polar
dielectrics is formulated, and the variation of temperature and entropy, the
absorption of heat, and the work under different electric fields are calculated
for BaTiO3, Pb(ZrxTi1-x)O3, P(VDF-TrFE), and water. And the simulation results
obtained agree well with the recently published experimental data [B. Neese, et
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