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Matt Pharr's picture

In-situ measurements of stress evolution in composite sulfur cathodes

Owing to their enormous capacities, Li-S batteries have emerged as a prime candidate for economic and sustainable energy storage. Still, potential mechanics-based issues exist that must be addressed: lithiation of sulfur produces an enormous volume expansion (~80%). In other high capacity electrodes, large expansions generate considerable stresses that can lead to mechanical damage and capacity fading.

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