http://dx.doi.org/10.1142/S1758825116500216Molecular dynamics (MD) simulations are performed to investigate the adsorption mechanics and conformational dynamics of single and multiple bovine serum albumin (BSA) peptide segments on single-layer graphene through analysis of parameters such as the root-mean-square displacements, number of hydrogen bonds, helical content, inter- action energies, and motions of mass center of the peptides.
The Poisson's ratio characterizes the resultant strain in the lateral direction for a material under longitudinal deformation. Though negative Poisson's ratios (NPR) are theoretically possible within continuum elasticity, they are most frequently observed in engineered materials and structures, as they are not intrinsic to many materials. In this work, we report NPR in single-layer graphene ribbons, which results from the compressive edge stress induced warping of the edges.
In the attached paper we have shown that graphene and carbon nanotubes are in a self-stress state in their natural equilibrium state, that is, the state prior to the application of external loads. We have identified different sources of self-stresses and accurately evaluated them; we have shown that they are by no means negligible with respect to load-related nanostresses.
http://pubs.acs.org/doi/abs/10.1021/acsami.5b05615 Studies reveal that biomolecules can form intriguing molecular structures with fascinating functionalities upon interaction with graphene. Then, interesting questions arise. How does silk fibroin interact with graphene? Does such interaction lead to an enhancement in its mechanical properties?
Recent experiments reveal that a scanning tunneling microscopy (STM) probe tip can generate a highly localized strain field in a graphene drumhead, which in turn leads to pseudomagnetic fields in the graphene that can spatially confine graphene charge carriers in a way similar to a lithographically defined quantum dot (QD). While these experimental findings are intriguing, their further implementation in nanoelectronic devices hinges upon the knowledge of key underpinning parameters, which still remain elusive.
The current paper focuses on investigating deformation mechanism of graphene sheets in a graphene reinforced polyethylene (Gn–PE) nanocomposite. Classical molecular dynamics (MD) simulation was conducted on large Gn–PE systems. Different spatial arrangements of graphene sheets were considered in order to study the effect of nonlocal interaction among the graphenes. In all the cases 5% weight concentration of graphene was considered in order to prepare atomistic models for Gn–PE.
In armchair graphene sheets, crack propagates perpendicular to the applied strain, whereas crack propagation in zigzag sheets occurs at an angle to the straining direction. This occurs due to different bond structure along armchair and zigzag directions as shown in Fig. 1. Videos 1 and 2 show the fracture of armchair and zigzag sheets, respectively.
Fig. 1: Armchair and zigzag directions of graohene
A post-Doc position is available on a project on Ensemble Monte Carlo simulations of graphene for power electronics applications for studying the effect of boundary scattering of charge carriers in graphene nanoribbons. The project is sponsored by the Office of Naval Research- global (ONR) - Department of Defense (DOD)- U.S. Navy.