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Zirconia

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Effects of specimen size and yttria concentration on mechanical properties of single crystalline yttria-stabilized tetragonal zirconia nanopillars

The nanoscale plastic deformation of yttria-stabilized tetragonal zirconia (YSTZ) is highly dependent on the crystallographic orientations, i.e., dislocation is induced when the loading direction is 45° tilted to {111} and {101} slip planes, while tetragonal to monoclinic phase transformation dominates the plastic deformation when loading direction is perpendicular to the slip planes.

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Competing mechanisms between dislocation and phase transformation in plastic deformation of single crystalline yttria-stabilized tetragonal zirconia nanopillars

Molecular dynamics (MD) is employed to investigate the plastic deformation mechanisms of single crystalline yttria-stabilized tetragonal zirconia (YSTZ) nanopillars under uniaxial compression. Simulation results show that the nanoscale plastic deformation of YSTZ is strongly dependent on the crystallographic orientation of zirconia nanopillars. For the first time, the experimental explored tetragonal to monoclinic phase transformation is reproduced by MD simulations in some particular loading directions.

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Shape memory effect and pseudoelasticity behavior in tetragonal zirconia polycrystals: A phase field study

Shape memory effect and pseudoelasticity behavior in tetragonal zirconia polycrystals: A phase field study, International Journal of Plasticity 60 (2014) 71–86. Martensitic tetragonal-to-monoclinic transformation in zirconia is a ‘‘double-edged sword’’, enabling transformation toughening or shape memory effects in favorable cases, but also cracks and phase degradation in undesirable scenarios.

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