Cardboard rolls on the nanoscale

Everybody knows that cardboard paper can be a highly
anisotropic material. You can easily bend or roll it in one direction
and it is stiff in the other. If you take a close look you will find
that the paper is periodically buckled along one direction. We have now
exploited this phenomenon on the nanoscale to define the roll-up
direction of ultra-thin membranes on a substrate surface.

The intrinsic manipulation of thin inorganic or organic nanomembranes (including graphene)

on substrate surfaces has attracted great attention over recent years, since it allows to shape

two-dimensional layers into functional 3D objects of virtually any material, geometry and size.



However, there are fundamental limits in this shaping procedure, one of which is the

direction of shaping. We consider the simplest case, which is a 2D layer of rectangular shape.

If this layer is stressed, it will bend only from the "long" edges. However, for many purposes

bending from the "short" edge would be required. As we demonstrate in our work both theoretically

and experimentally, this problem can be solved by appropriately wrinkling the flat layer. We develop

a phase diagram for the direction of bending depending on wrinkle amplitude and strain gradient,

and experimentally verify our theoretical predictions.

 

Our findings provide fundamentally new way of control over formation of scrolled films and

nanomembranes with defined geometry and chirality. This can advance fields and applications

of self-folding nanostructures, rolled-up nanotubes and

carbon nanoscrolls (made of graphene).

P. Cendula, S. Kiravittaya, I. Mönch, J. Schumann, O. G. Schmidt

Directional roll-up of nanomembranes mediated by wrinkling

Nano Lett. 11, 236 (2011)

PDF from arxiv.org is attached.