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Lithium ion battery; nanowire; nanobattery; in situ transmission electron microscopy; electrolyte; breakdown; space-charge limited conduction

Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries

Nano Lett., 2012, 12 (1), pp 505–511

 

Rechargeable, all-solid-state Li ion batteries (LIBs) with high specific
capacity and small footprint are highly desirable to power an emerging
class of miniature, autonomous microsystems that operate without a
hardwire for power or communications. A variety of three-dimensional
(3D) LIB architectures that maximize areal energy density has been
proposed to address this need. The success of all of these designs
depends on an ultrathin, conformal electrolyte layer to electrically

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