suo group research

Active polymers are being developed to mimic a salient feature of life: movement in response to stimuli. Large deformation can lead to intriguing phenomena; for example, recent experiments have shown that a voltage can deform a layer of a dielectric elastomer into two coexistent states, one being flat and the other wrinkled. This observation, as well as the needs to analyze large deformation under diverse stimuli, has led us to reexamine the theory of electromechanics.

As another celebration of March Journal Club of Mechanics of Flexible Electronics, this paper has just been submitted.

Abstract 

In one design of flexible electronics, thin-film islands of a stiff material are fabricated on a polymeric substrate, and functional materials are grown on these islands. When the substrate is stretched, the deformation is mainly accommodated by the substrate, and the islands and functional materials experience relatively small strains. Experiments have shown that, however, for a given amount of stretch, the islands exceeding a certain size may delaminate from the substrate. We calculate the energy release rate using a combination of finite element method and complex variable method. Our results show that the energy release rate diminishes as the island size or substrate stiffness decreases. Consequently, the critical island size is large when the substrate is compliant. We also obtain an analytical expression for the energy release rate of debonding islands from a very compliant substrate.

by Juil Yoon, Zhen Zhang, Nanshu Lu, Zhigang Suo

As well pointed out by Journal Club of March 2007, the flexible electronics is an emerging technology.

By Martijn Feron, Zhen Zhang and Zhigang Suo

The mobility of charge carriers in silicon can be significantly increased when silicon is subject to a field of strain.In a microelectronic device, however, the strain field may be intensified at a sharp feature, such as an edge or a corner, injecting dislocations into silicon and ultimately failing the device. The strain field at an edge is singular, and is often a linear superposition of two modes of different exponents. We characterize the relative contribution of the two modes by a mode angle, and determine the critical slip systems as the amplitude of the load increases. We calculate the critical residual stress in a thin-film stripe bonded on a silicon substrate.

In continuum mechanics, it is a common practice to view a body as a field of material particles, so that the continuum mechanics is phrased as an algorithm to determine the function x(X, t), where X is the name of a particle, and x is the place of the particle at time t.

Abstract: Flexible electronic devices often require hermetic coatings that can withstand applied strains. This paper calculates the critical strains for various configurations of channel cracks in a coating consisting of organic and inorganic layers. We show that the coating can sustain the largest strain when the organic layer is of some intermediate thicknesses.

Flexible electronics are promising for diverse applications, such as rollable displays, conformal sensors, and printable solar cells. These systems are thin, rugged, and lightweight. They can be manufactured at low costs, for example, by roll-to-roll printing. The development of flexible electronics has raised many issues concerning the mechanical behavior of materials. This paper examines a particular issue: channel cracks in hermetic coatings.

Electronic devices (e.g., organic light-emitting devices, OLEDs) often degrade when exposed to air. Developing hermetic coatings has been a significant challenge. Organic films are permeable to gases, and inorganic films inevitably contain processing flaws, so that neither by themselves are effective gas barriers. These considerations have led to the development of multilayer coatings consisting of alternating organic and inorganic films. To be used in flexible electronics, these coatings must also withstand applied strains without forming channel cracks...

Teng Li, Zhenyu Huang, Zhichen Xi, Stephanie P. Lacour, Sigurd Wagner, Zhigang Suo, Mechanics of Materials, 37, 261-273 (2005).

Under tension, a freestanding thin metal film usually ruptures at a smaller strain than its bulk counterpart. Often this apparent brittleness does not result from cleavage, but from strain localization, such as necking. By volume conservation, necking causes local elongation. This elongation is much smaller than the film length, and adds little to the overall strain. The film ruptures when the overall strain just exceeds the necking initiation strain, ε_N , which for a weakly hardening film is not far beyond its elastic limit. Now consider a weakly hardening metal film on a steeply hardening polymer substrate. If the metal film is fully bonded to the polymer substrate, the substrate suppresses large local elongation in the film, so that the metal film may deform uniformly far beyond ε_N. If the metal film debonds from the substrate, however, the film becomes freestanding and ruptures at a smaller strain than the fully bonded film; the polymer substrate remains intact. We study strain delocalization in the metal film on the polymer substrate by analyzing incipient and large-amplitude nonuniform deformation, as well as debond-assisted necking. The theoretical considerations call for further experiments to clarify the rupture behavior of the metal-on-polymer laminates.

Related posts and discussions

Tension of Cu film on Pi substrate
Local thinning of Cu film
High ductility of a metal film adherent on a polymer substrate

Zhigang Suo, Xuanhe Zhao, and William H. Greene

T. Zhu, Z. Suo, A. Winkleman, G. M. Whitesides, Applied Physics Letters, 88, 144101, (2006)

Gold films on an elastomeric substrate can be stretched and relaxed reversibly by tens of percents. The films initially form in two different structures, one continuous and the other containing tri-branched microcracks. We have identified the mechanism of elastic stretchability in the films with microcracks. The metal, which is much stiffer than the elastomer, forms a percolating network.