'Sideways' and stable crack propagation in a silicone elastomer

We have discovered a peculiar form of fracture that occurs in a highly stretchable silicone elastomer (Smooth-On Ecoflex 00–30). Under certain conditions, cracks propagate in a direction perpendicular to the initial pre-cut and in the direction of the applied load. In other words, the crack deviates from the standard trajectory and instead propagates perpendicular to that trajectory. The crack arrests stably, and thus the material ahead of the crack front continues to sustain load, thereby enabling enormous stretchabilities. We call this phenomenon 'sideways' and stable cracking. To explain this behavior, we first perform finite-element simulations that demonstrate a propensity for sideways cracking, even in an isotropic material. The simulations also highlight the importance of crack-tip blunting on the formation of sideways cracks. Next, we provide a hypothesis on the origin of sideways cracking that relates to microstructural anisotropy (in a nominally isotropic elastomer). To substantiate this hypothesis, we transversely pre-stretch samples to various extents before fracture testing, as to determine the influence of microstructural arrangement (chain alignment and strain-induced crystallization) on fracture energy. We also perform microstructural characterization that indicates that significant chain alignment and strain-induced crystallization indeed occur in this material upon stretching. We conclude by characterizing how a number of loading conditions, such as sample geometry and strain rate, affect this phenomenon. Overall, this paper provides fundamental mechanical insight into basic phenomena associated with fracture of elastomers.

The paper can has been published in PNAS and can be found here: https://esml.tamu.edu/?page_id=12

or here: https://www.pnas.org/content/116/19/9251.short