In an article published in the August 20 issue of Nature Communications, we report a mechanochemical phenomenon in graphene oxide membranes, covalent epoxide-to-ether functional group transformations that deviate from epoxide ring-opening reactions, discovered through nanomechanical experiments and density functional-based tight binding calculations.
The fatigue behavior of Ag films on polyethyleneterephthalate substrates was studied using electrical resistance measurements.
Scanning electron microscopy images showed two types of failure: typical fatigue failure with extrusion–intrusion pairs, and ductile
failure with local necking. Once through-thickness cracks are formed in the metal layer, cracks propagate and the resistance increases abruptly for both failure modes. The effect of adhesion on fatigue life is discussed in terms of concurrent delamination, crack initiation and propagation.
We study the effects of grain boundary adhesion and grain size on the ductility of thin metal films well bonded to polymer substrates, using finite element method. It is shown that the ductility of polymer-supported metal films increases approximately linearly as the grain boundary adhesion increases, and as the grain size decreases. A rule-of-thumb estimate of the ductility of polymer-supported metal films agrees well with the simulation results.
In press, Scripta Materialia, 2008
Zhigang Suo, Joost Vlassak, and Sigurd Wagner
