Flexoelectricity

Abstract

This paper presents a design methodology based on a combination of isogeometric analysis (IGA),

level set and point wise density mapping techniques for topology optimization of piezoelectric /

flexoelectric materials. The fourth order partial differential equations (PDEs) of flexoelectricity,

which require at least C 1 continuous approximations, are discretized using Non-Uniform Rational

B-spline (NURBS). The point wise density mapping technique with consistent derivatives is

This work has been recently published in Nature Nanotechnology. 

Cracks generate the largest strain gradients that any material can withstand. Flexoelectricity (coupling between strain gradient and polarization) must therefore play an important role in fracture physics. Here we use a self-consistent continuum model to evidence two consequences of flexoelectricity in fracture: the resistance to fracture increases as structural size decreases, and it becomes asymmetric with respect to the sign of polarization. The latter phenomenon manifests itself in a range of intermediate sizes where piezo- and flexoelectricity compete.

Flexoelectricity is an electromechanical effect coupling polarization to strain gradients. It fundamentally differs from piezoelectricity because of its size-dependence and symmetry. Flexoelectricity is generally perceived as a small effect noticeable only at the nanoscale. Since ferroelectric ceramics have a particularly high flexoelectric coefficient, however, it may play a significant role as piezoelectric transducers shrink to the sub-micrometer scale. We examine this issue with a continuum model self-consistently treating piezo- and flexoelectricity.

Flexoelectricity is a universal property of all dielectrics by which they generate a voltage in response to an inhomogeneous deformation. One of the controversial issues in this field concerns the magnitude of flexoelectric coefficients measured experimentally, which greatly exceed theoretical estimates. Furthermore, there is a broad scatter amongst experimental measurements. The truncated pyramid compression method is one of the common setups to quantify flexoelectricity, the interpretation of which relies on simplified analytical equations to estimate strain gradients.

Flexoelectricity is a size-dependent electromechanical mechanism coupling polarization and strain gradient. It exists in a wide variety of materials, and is most noticeable for nanoscale objects, where strain gradients are higher. Simulations are important to understand flexoelectricity because experiments at very small scales are difficult, and analytical solutions are scarce. Here, we computationally evaluate the role of flexoelectricity in the electromechanical response of linear dielectric solids in two-dimensions.

Most technologically relevant ferroelectrics typically lose piezoelectricity above the Curie temperature. This limits their use to relatively low temperatures. In this Letter, exploiting a combination of flexoelectricity and simple functional grading, we propose a strategy for high-temperature electromechanical coupling in a standard thin film configuration.

In a piezoelectric material an applied uniform strain can induce an electric polarization (or vice-versa). Crystallographic considerations restrict this technologically important property to non-centrosymmetric systems. It can be shown both mathematically and physically, that a non-uniform strain can potentially break the inversion symmetry and induce polarization even in non-piezoelectric dielectrics.